Ultrasmall Functionalized UiO-66 Nanoparticle/Polymer Pebax 1657 Thin-Film Nanocomposite Membranes for Optimal CO2 Separation

Martínez-Izquierdo, Lidia ; García-Comas, Cristina ; Dai, Shan ; Navarro, Marta ; Tissot, Antoine ; Serre, Christian ; Téllez, Carlos (Universidad de Zaragoza) ; Coronas, Joaquín (Universidad de Zaragoza)

Resumen: Ultrasmall 4 to 6 nm nanoparticles of the metal–organic framework (MOF) UiO-66 (University of Oslo-66) were successfully prepared and embedded into the polymer Pebax 1657 to fabricate thin-film nanocomposite (TFN) membranes for CO2/N2 and CO2/CH4 separations. Furthermore, it has been demonstrated that ligand functionalization with amino (−NH2) and nitro (−NO2) groups significantly enhances the gas separation performance of the membranes. For CO2/N2 separation, 7.5 wt % UiO-66-NH2 nanoparticles provided a 53% improvement in CO2 permeance over the pristine membrane (from 181 to 277 GPU). Regarding the CO2/N2 selectivity, the membranes prepared with 5 wt % UiO-66-NO2 nanoparticles provided an increment of 17% over the membrane without the MOF (from 43.5 to 51.0). However, the CO2 permeance of this membrane dropped to 155 GPU. The addition of 10 wt % ZIF-94 particles with an average particle size of ∼45 nm into the 5 wt % UiO-66-NO2 membrane allowed to increase the CO2 permeance to 192 GPU while maintaining the CO2/N2 selectivity at ca. 51 due to the synergistic interaction between the MOFs and the polymer matrix provided by the hydrophilic nature of ZIF-94. In the case of CO2/CH4 separation, the 7.5 wt % UiO-66-NH2 membrane exhibited the best performance with an increase of the CO2 permeance from 201 to 245 GPU.

Idioma: Inglés

DOI: 10.1021/acsami.3c16093

Año: 2024

Publicado en: ACS applied materials & interfaces 16, 3 (2024), 4024-4034
ISSN: 1944-8244

Financiación: info:eu-repo/grantAgreement/ES/DGA/T68-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033
Financiación: info:eu-repo/grantAgreement/EUR/MICINN/TED2021-130621B-C41

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)