ZIF-8 modified with 2-undecylimidazolate as filler for mixed matrix membranes for CO<sub>2</sub> separation
Pérez-Miana, Marta (Universidad de Zaragoza) ; Luque-Alled, José Miguel (Universidad de Zaragoza) ; Yahia, Mohamed ; Mayoral, Álvaro ; Coronas, Joaquín (Universidad de Zaragoza)
Resumen: A novel modification of zeolitic imidazolate framework-8 (ZIF-8) with 2-undecylimidazolate (umIm) was explored to enhance its hydrophobic character and improve its compatibility with polymer of intrinsic microporosity PIM-1 when incorporated as a filler in mixed matrix membranes (MMMs). In addition to the study of the best conditions to exchange the structural ligand of ZIF-8 by umIm and the characterization (by FTIR, RMN, XRD, TGA, N2 adsorption and TEM) of the obtained material, comparative analyses were conducted using MMMs containing the original ZIF-8 and the modified version. Different loadings were applied to study the impact on gas separation properties. Remarkably, the MMM with the modified ZIF-8 demonstrated superior performance surpassing the Robeson upper bound line of 2008 and revealing the effectiveness of this MOF modification strategy. In fact, with the 10 wt% ZIF-8-umIm loading MMM, the highest value of CO2/N2 selectivity was 15.4 (12% higher than that of bare PIM-1) at a CO2 permeability of 16 667 Barrer (52% higher than that of bare PIM-1). These findings highlight the promising potential of the ZIF-8 modification with umIm as a valuable filler material for MMMs in gas separation applications.
Idioma: Inglés
DOI: 10.1039/d3ta07109j
Año: 2024
Publicado en: Journal of Materials Chemistry A 12, 17 (2024), 10316-10328
ISSN: 2050-7488
Factor impacto JCR: 9.5 (2024)
Categ. JCR: CHEMISTRY, PHYSICAL rank: 33 / 185 = 0.178 (2024) - Q1 - T1
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 63 / 460 = 0.137 (2024) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 29 / 182 = 0.159 (2024) - Q1 - T1
Factor impacto SCIMAGO: 2.462 - Chemistry (miscellaneous) (Q1) - Renewable Energy, Sustainability and the Environment (Q1) - Materials Science (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E13-23R
Financiación: info:eu-repo/grantAgreement/ES/DGA/T68-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2022-138582OB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I
Financiación: info:eu-repo/grantAgreement/EUR/MICINN/TED2021-130621B-C41
Tipo y forma: Article (Published version)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2025-09-22-14:40:29)
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Idioma: Inglés
DOI: 10.1039/d3ta07109j
Año: 2024
Publicado en: Journal of Materials Chemistry A 12, 17 (2024), 10316-10328
ISSN: 2050-7488
Factor impacto JCR: 9.5 (2024)
Categ. JCR: CHEMISTRY, PHYSICAL rank: 33 / 185 = 0.178 (2024) - Q1 - T1
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 63 / 460 = 0.137 (2024) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 29 / 182 = 0.159 (2024) - Q1 - T1
Factor impacto SCIMAGO: 2.462 - Chemistry (miscellaneous) (Q1) - Renewable Energy, Sustainability and the Environment (Q1) - Materials Science (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E13-23R
Financiación: info:eu-repo/grantAgreement/ES/DGA/T68-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2022-138582OB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I
Financiación: info:eu-repo/grantAgreement/EUR/MICINN/TED2021-130621B-C41
Tipo y forma: Article (Published version)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2025-09-22-14:40:29)
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Record created 2024-05-16, last modified 2025-09-23