A family of Lanthanoid-Sodium multifunctional coordination polymers: single-molecule magnet, luminescent and magnetocaloric properties

Troyano, Alejandro Cuesta ; González, Jonay ; Arauzo, Ana (Universidad de Zaragoza) ; Bartolomé, Elena ; Sañudo, E. Carolina

Resumen: In this paper we report the microwave assisted synthesis and characterization of a family of Na−Ln coordination polymers (CPs) of formula [NaDy2(MeCOO)2(SALOH)5(chpH)2] (1Ln, Ln=Eu, Gd, Tb, Dy, Ho, Y). The Na+ cations isolate Ln2 units in a one‐dimensional polymer. By changing the lanthanoid ions, we attain Single Molecule Magnet properties (1Dy), luminescent properties (1Eu, 1Tb, 1Ho), a diamagnetic material (1Y) and a material that presents magnetocaloric effect (1Gd).

Idioma: Inglés

DOI: 10.1002/ejic.202300719

Año: 2024

Publicado en: European Journal of Inorganic Chemistry 27, 14 (2024), e202300719 [8 pp.]
ISSN: 1434-1948

Factor impacto JCR: 2.0 (2024)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 24 / 42 = 0.571 (2024) - Q3 - T2

Factor impacto SCIMAGO: 0.459 - Inorganic Chemistry (Q2)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E12-23R-RASMIA

Tipo y forma: Article (Published version)

Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)