Exploring Ferrocenyl Imine-Phosphane Complexes in Gold(I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant
Pérez-Sánchez, Juan Carlos ; Pérez Herrera, Raquel ; Gimeno, M. Concepción
Resumen: Another class of gold(I) redox‐switchable catalysts, incorporating ferrocenyl phosphane‐imines, enriches the existing library of gold(I) complexes. Our catalyst proves efficacy in gold(I)‐catalyzed cyclizations of furans and benzamides, exhibiting reversible “on‐off” switching. Furthermore, we explored the unconventional role of “Magic Blue”, commonly used as an oxidizing agent in various organic transformations, as a potential activator of the Au−Cl bond, initiating conventional gold(I) catalysis.
Idioma: Inglés
DOI: 10.1002/adsc.202400593
Año: 2024
Publicado en: Advanced Synthesis and Catalysis 366, 18 (2024), 3845-3852
ISSN: 1615-4150
Factor impacto JCR: 4.0 (2024)
Categ. JCR: CHEMISTRY, ORGANIC rank: 8 / 57 = 0.14 (2024) - Q1 - T1
Categ. JCR: CHEMISTRY, APPLIED rank: 22 / 75 = 0.293 (2024) - Q2 - T1
Factor impacto SCIMAGO: 0.93 - Organic Chemistry (Q1) - Catalysis (Q2)
Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888
Financiación: info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2025-09-22-14:43:53)
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Idioma: Inglés
DOI: 10.1002/adsc.202400593
Año: 2024
Publicado en: Advanced Synthesis and Catalysis 366, 18 (2024), 3845-3852
ISSN: 1615-4150
Factor impacto JCR: 4.0 (2024)
Categ. JCR: CHEMISTRY, ORGANIC rank: 8 / 57 = 0.14 (2024) - Q1 - T1
Categ. JCR: CHEMISTRY, APPLIED rank: 22 / 75 = 0.293 (2024) - Q2 - T1
Factor impacto SCIMAGO: 0.93 - Organic Chemistry (Q1) - Catalysis (Q2)
Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888
Financiación: info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2025-09-22-14:43:53)
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Record created 2024-08-29, last modified 2025-09-23