000144702 001__ 144702
000144702 005__ 20251204145008.0
000144702 0247_ $$2doi$$a10.1002/cplu.202400162
000144702 0248_ $$2sideral$$a139535
000144702 037__ $$aART-2024-139535
000144702 041__ $$aeng
000144702 100__ $$0(orcid)0000-0002-1430-1440$$aBatuecas, María$$uUniversidad de Zaragoza
000144702 245__ $$aRecent advances on the chemistry of transition metal complexes with monoanionic bidentate silyl ligands
000144702 260__ $$c2024
000144702 5060_ $$aAccess copy available to the general public$$fUnrestricted
000144702 5203_ $$aThe chemistry of transition-metal (TM) complexes with monoanionic bidentate (κ2-L,Si) silyl ligands has considerably grown in recent years. This work summarizes the advances in the chemistry of TM-(κ2-L,Si) complexes (L=N-heterocycle, phosphine, N-heterocyclic carbene, thioether, ester, silylether or tetrylene). The most common synthetic method has been the oxidative addition of the Si−H bond to the metal center assisted by the coordination of L. The metal silicon bond distances in TM-(κ2-L,Si) complexes are in the range of metal-silyl bond distances. TM-(κ2-L,Si) complexes have proven to be effective catalysts for hydrosilylation and/or hydrogenation of unsaturated molecules among other processes.
000144702 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/EC/H2020/101034288/EU/International Fellowship Programme for Talent Attraction to the Campus of International Excellence Campus Iberus/IberusExperience$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 101034288-IberusExperience$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00
000144702 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000144702 590__ $$a2.8$$b2024
000144702 592__ $$a0.73$$b2024
000144702 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b114 / 239 = 0.477$$c2024$$dQ2$$eT2
000144702 593__ $$aChemistry (miscellaneous)$$c2024$$dQ2
000144702 655_4 $$ainfo:eu-repo/semantics/review$$vinfo:eu-repo/semantics/publishedVersion
000144702 700__ $$aGoméz-España, Alejandra
000144702 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Álvarez, Francisco J.$$uUniversidad de Zaragoza
000144702 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000144702 773__ $$g89, 9 (2024), e202400162 [22 pp.]$$pChemPlusChem$$tChemPlusChem$$x2192-6506
000144702 8564_ $$s7038443$$uhttps://zaguan.unizar.es/record/144702/files/texto_completo.pdf$$yVersión publicada
000144702 8564_ $$s1897153$$uhttps://zaguan.unizar.es/record/144702/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000144702 909CO $$ooai:zaguan.unizar.es:144702$$particulos$$pdriver
000144702 951__ $$a2025-12-04-14:45:28
000144702 980__ $$aARTICLE