Mixed matrix membranes comprising glassy polymers and dispersed mesoporous silica spheres for gas separation
Zornoza, B. (Universidad de Zaragoza) ; Téllez, C. (Universidad de Zaragoza) ; Coronas, J. (Universidad de Zaragoza)
Resumen: Mixed matrix membranes (MMMs) composed of polyimide Matrimid® and mesoporous silica spheres (MSSs) are prepared, characterized and tested in gas separation of equimolar mixtures H2/CH4 and CO2/N2 at different temperatures. Their performance is compared with MMMs using other glassy polymer: polysulfone Udel®. The convenience of removing the structural agent from the pores and activating the mesoporous with calcination or chemical extraction has been studied. In both studied polymers, the permeability of the selective gas increases with the filler and the selectivity has a maximum at 8 wt% filler loading. These improvements are related to the mesoporosity of the filler, good interaction between the filler and the polymer, and change in the polymer structure as indicated in the characterization done by thermogravimetric analysis, X-ray diffraction, differential scanning calorimetry, and scanning and transmission electron microscopy.
Idioma: Inglés
DOI: 10.1016/j.memsci.2010.11.027
Año: 2011
Publicado en: JOURNAL OF MEMBRANE SCIENCE 368, 1-2 (2011), 100-109
ISSN: 0376-7388
Factor impacto JCR: 3.85 (2011)
Categ. JCR: POLYMER SCIENCE rank: 11 / 79 = 0.139 (2011) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 8 / 132 = 0.061 (2011) - Q1 - T1
Financiación: info:eu-repo/grantAgreement/ES/MICINN/MAT2007-61028
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
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Idioma: Inglés
DOI: 10.1016/j.memsci.2010.11.027
Año: 2011
Publicado en: JOURNAL OF MEMBRANE SCIENCE 368, 1-2 (2011), 100-109
ISSN: 0376-7388
Factor impacto JCR: 3.85 (2011)
Categ. JCR: POLYMER SCIENCE rank: 11 / 79 = 0.139 (2011) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 8 / 132 = 0.061 (2011) - Q1 - T1
Financiación: info:eu-repo/grantAgreement/ES/MICINN/MAT2007-61028
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2025-01-20-14:54:24)
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Record created 2025-01-20, last modified 2025-01-20