Green synthesis of starch-capped Cu2O nanocubes and their application in the direct electrochemical detection of glucose
Jiménez-Rodríguez A. ; Sotelo E. ; Martínez L. ; Huttel Y. ; Ujué González M. ; Mayoral A. (Universidad de Zaragoza) ; García-Martín J.M. ; Videa M. ; Cholula-Díaz J.L.
Resumen: Glucose determination is an essential procedure in different fields, used in clinical analysis for the prevention and monitoring of diabetes. In this work, modified carbon paste electrodes with Cu2O nanocubes (Cu2O NCs) were developed to test electrochemical glucose detection. The synthesis of the Cu2O NCs was achieved by a green method using starch as the capping agent, obtaining cubic-like morphologies and particle sizes from 227 to 123 nm with increasing amounts of the capping agent, as corroborated by electron microscopy analysis. Their crystalline structure and purity were determined by X-ray diffraction. The capability of starch as a capping agent was verified by Fourier-transform infrared spectroscopy, in which the presence of functional groups of this biopolymer in the Cu2O NCs were identified. The electrochemical response to glucose oxidation was determined by cyclic voltammetry, obtaining a linear response of the electrical current as a function of glucose concentration in the range 100-700 µM, with sensitivities from 85.6 to 238.8 µA mM-1cm-2, depending on the amount of starch used in the synthesis of the Cu2O NCs.
Idioma: Inglés
DOI: 10.1039/d0ra10054d
Año: 2021
Publicado en: RSC Advances 11, 23 (2021), 13711-13721
ISSN: 2046-2069
Factor impacto JCR: 4.036 (2021)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 75 / 179 = 0.419 (2021) - Q2 - T2
Factor impacto CITESCORE: 5.9 - Chemical Engineering (Q2)
Factor impacto SCIMAGO: 0.667 - Chemistry (miscellaneous) (Q1) - Chemical Engineering (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/CSIC/i-Link+2019-LINKB20024
Financiación: info:eu-repo/grantAgreement/ES/DGA/E13-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2025-10-17-14:18:04)
Visitas y descargas
Idioma: Inglés
DOI: 10.1039/d0ra10054d
Año: 2021
Publicado en: RSC Advances 11, 23 (2021), 13711-13721
ISSN: 2046-2069
Factor impacto JCR: 4.036 (2021)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 75 / 179 = 0.419 (2021) - Q2 - T2
Factor impacto CITESCORE: 5.9 - Chemical Engineering (Q2)
Factor impacto SCIMAGO: 0.667 - Chemistry (miscellaneous) (Q1) - Chemical Engineering (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/CSIC/i-Link+2019-LINKB20024
Financiación: info:eu-repo/grantAgreement/ES/DGA/E13-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2025-10-17-14:18:04)
Permalink:
Visitas y descargas
Este artículo se encuentra en las siguientes colecciones:
Articles > Artículos por área > Física de la Materia Condensada
Record created 2025-02-27, last modified 2025-10-17