Resumen: The almost-two-centuries history of spectrochemical analysis has generated a body of literature so vast that it has become nearly intractable for experts, much less for those wishing to enter the field. Authoritative, focused reviews help to address this problem but become so granular that the overall directions of the field are lost. This broader perspective can be provided partially by general overviews but then the thinking, experimental details, theoretical underpinnings, and instrumental innovations of the original work must be sacrificed. In the present compilation, this dilemma is overcome by assembling the most impactful publications in the area of analytical atomic spectrometry. Each entry was proposed by at least one current expert in the field and supported by a narrative that justifies its inclusion. The entries were then assembled into a coherent sequence and returned to contributors for a round-robin review. A total of 48 scientists participated in this endeavor, contributing a combined list of 1055 individual articles spanning 17 sub-disciplines of spectrochemical analysis into what the current community views as “key” publications. Of these cited articles, 60 received nominations from four or more scientists, establishing them as the most indispensable reading materials. The outcome of this collaborative effort is intended to serve as a valuable resource not only for current practitioners in atomic spectroscopy but also for present and future students who represent coming generations of analytical atomic spectroscopists. Idioma: Inglés DOI: 10.1177/00037028241263567 Año: 2024 Publicado en: APPLIED SPECTROSCOPY 79, 4 (2024), 481-735 ISSN: 0003-7028 Factor impacto JCR: 2.2 (2024) Categ. JCR: SPECTROSCOPY rank: 16 / 44 = 0.364 (2024) - Q2 - T2 Categ. JCR: INSTRUMENTS & INSTRUMENTATION rank: 40 / 79 = 0.506 (2024) - Q3 - T2 Factor impacto SCIMAGO: 0.456 - Instrumentation (Q2) - Spectroscopy (Q3)