An à la Carte Synthesis Approach for Chemically Linking Au, Pt, and Pd Nanoparticles to Few‐Layer 2H‐MoS

Quirós-Ovies, Ramiro ; Bonet, Javier ; Pérez, Emilio M. ; Santamaría, Jesús (Universidad de Zaragoza) ; Sebastián, Víctor (Universidad de Zaragoza)

Resumen: The combination of 2D materials and metallic nanoparticles (NPs) enables the creation of hybrid systems with enhanced properties, such as improved light absorption via plasmon resonance or the introduction of active catalytic sites. However, effectively interfacing 2D materials with NPs remains challenging. This work presents a novel and efficient à la carte synthesis approach that enables the tailored chemical linkage of noble metal NPs—gold (Au), platinum (Pt), and palladium (Pd)— to ultrathin 2H-MoS2 sheets using orthogonal maleimide-based linkers. Specifically, alkyne-, carboxylic acid-, and phenyl bromide-terminated maleimides are employed to anchor Au, Pt, and Pd NPs, respectively. This modular strategy allows precise control over the surface chemistry, leading to uniform decoration with sub-2 nm NPs and robust attachment to the MoS2 substrate. This chemical linkage is expected to enhance the interaction between the MoS2 and the NPs while also improving the mechanical stability of the hybrid material. These combined effects make the system particularly promising for applications requiring both strong interfacial coupling and durability, such as electrocatalysis, sensing, and flexible electronic devices.

Idioma: Inglés

DOI: 10.1002/smll.202508348

Año: 2025

Publicado en: Small 21, 51 (2025), e08348 [12 pp.]
ISSN: 1613-6810

Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-127847OB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2024-1603390B-100
Financiación: info:eu-repo/grantAgreement/ES/MICIU/CEX2023-001286-S

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)