000167901 001__ 167901
000167901 005__ 20260128154426.0
000167901 0247_ $$2doi$$a10.1002/smll.202508348
000167901 0248_ $$2sideral$$a147333
000167901 037__ $$aART-2025-147333
000167901 041__ $$aeng
000167901 100__ $$aQuirós-Ovies, Ramiro
000167901 245__ $$aAn à la Carte Synthesis Approach for Chemically Linking Au, Pt, and Pd Nanoparticles to Few‐Layer 2H‐MoS
000167901 260__ $$c2025
000167901 5203_ $$aThe combination of 2D materials and metallic nanoparticles (NPs) enables the creation of hybrid systems with enhanced properties, such as improved light absorption via plasmon resonance or the introduction of active catalytic sites. However, effectively interfacing 2D materials with NPs remains challenging. This work presents a novel and efficient à la carte synthesis approach that enables the tailored chemical linkage of noble metal NPs—gold (Au), platinum (Pt), and palladium (Pd)— to ultrathin 2H-MoS2 sheets using orthogonal maleimide-based linkers. Specifically, alkyne-, carboxylic acid-, and phenyl bromide-terminated maleimides are employed to anchor Au, Pt, and Pd NPs, respectively. This modular strategy allows precise control over the surface chemistry, leading to uniform decoration with sub-2 nm NPs and robust attachment to the MoS2 substrate. This chemical linkage is expected to enhance the interaction between the MoS2 and the NPs while also improving the mechanical stability of the hybrid material. These combined effects make the system particularly promising for applications requiring both strong interfacial coupling and durability, such as electrocatalysis, sensing, and flexible electronic devices.
000167901 536__ $$9info:eu-repo/grantAgreement/ES/MICIU/CEX2023-001286-S$$9info:eu-repo/grantAgreement/ES/MICINN/PID2024-1603390B-100$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-127847OB-I00
000167901 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000167901 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000167901 700__ $$0(orcid)0000-0002-1791-0188$$aBonet, Javier
000167901 700__ $$aPérez, Emilio M.
000167901 700__ $$0(orcid)0000-0002-8701-9745$$aSantamaría, Jesús$$uUniversidad de Zaragoza
000167901 700__ $$0(orcid)0000-0002-6873-5244$$aSebastián, Víctor$$uUniversidad de Zaragoza
000167901 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000167901 773__ $$g21, 51 (2025), e08348 [12 pp.]$$pSmall$$tSmall$$x1613-6810
000167901 8564_ $$s2298741$$uhttps://zaguan.unizar.es/record/167901/files/texto_completo.pdf$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-11-19
000167901 8564_ $$s2635998$$uhttps://zaguan.unizar.es/record/167901/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-11-19
000167901 909CO $$ooai:zaguan.unizar.es:167901$$particulos$$pdriver
000167901 951__ $$a2026-01-28-15:42:25
000167901 980__ $$aARTICLE