Novel aspects in the pyrolysis and oxidation of 2, 5-dimethylfuran

Alexandrino, K. (Universidad de Zaragoza) ; Millera, Á. (Universidad de Zaragoza) ; Bilbao, R. (Universidad de Zaragoza) ; Alzueta, M. U. (Universidad de Zaragoza)

Resumen: In order to contribute to the study of the behavior of 2,5-dimethylfuran (2,5-DMF), a promising biofuel to be used as fuel or additive in automotive applications, an experimental and kinetic modeling study of the pyrolysis and oxidation of 2,5-DMF has been carried out using well controlled flow reactor installations. The influence of temperature, stoichiometry, 2,5-DMF concentration, and pressure has been analyzed. A detailed chemical kinetic mechanism built from different literature sources was used to describe the pyrolysis and oxidation of 2,5-DMF under the experimental conditions studied. Results attained extend the existing experimental database on 2,5-DMF and, for the first time, its tendency to form soot is analyzed. Additionally, the effect of pressure, which would be of interest for the use of this compound as a part of diesel fuels, has been evaluated.

Idioma: Inglés

DOI: 10.1016/j.proci.2014.06.002

Año: 2015

Publicado en: PROCEEDINGS OF THE COMBUSTION INSTITUTE 35, 2 (2015), 1717-1725
ISSN: 1540-7489

Factor impacto JCR: 4.12 (2015)

Categ. JCR: ENERGY & FUELS rank: 17 / 88 = 0.193 (2015) - Q1 - T1
Categ. JCR: THERMODYNAMICS rank: 5 / 57 = 0.088 (2015) - Q1 - T1
Categ. JCR: ENGINEERING, MECHANICAL rank: 4 / 131 = 0.031 (2015) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 16 / 135 = 0.119 (2015) - Q1 - T1

Factor impacto SCIMAGO: 2.515 - Chemical Engineering (miscellaneous) (Q1) - Physical and Theoretical Chemistry (Q1) - Mechanical Engineering (Q1)

Tipo y forma: Article (PostPrint)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)