Nbu4((Au(C6F5)(3))(2)(Mu-PPh2)) - a Gold(III) Phosphide with a Single-Atom Bridging the Metallic Centers

Blanco, M.C. ; Fernandez, E.J. ; Fischer, A.K. ; Jones, P.G. ; Laguna, A. (Universidad de Zaragoza) ; Olmos, M.E. ; Villacampa, M.D. (Universidad de Zaragoza)

Resumen: Reaction of [Au(C6F5)3(PPh2H)] with [Au(C6F5)3(tht)] and NBu4(acac) (acac=acetylacetonate) leads to the synthesis of NBu4[{Au(C6F5)3}2(μ-PPh2)] (1), an unprecedented complex with two gold(III) centers bonded to a unique bridging atom without any other stabilizing effect. The novel di-bridged gold(III) phosphide [Au2(C6F5)4(μ-PPh2)2] (2) is obtained by treatment of diphenylphosphine with [Au2(C6F5)4(μ-Cl)2]. The crystal structures of both derivatives have been determined by X-ray diffraction.

Idioma: Inglés

Año: 2000

Publicado en: INORGANIC CHEMISTRY COMMUNICATIONS 3, 4 (2000), 163-165
ISSN: 1387-7003

Factor impacto JCR: 1.09 (2000)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 21 / 38 = 0.553 (2000) - Q3 - T2

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)