Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes

Burgess, Samantha A. ; Bolaño, Tamara (Universidad de Zaragoza) ; Gunnoe, T. Brent ; Sabat, Michal ; Myers, William H.

Resumen: The octahedral RhIII complexes [(tbpy)2Rh(XH)2][OTf]3 (tbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridyl; X = NHPh or OH; OTf = trifluoromethanesulfonate), [(tbpy)2Rh(X)2][OTf] (X = NHPh or OH), [(tbpy)2Rh(NHPh)(NH2Ph)][OTf]2, [(tbpy)2Rh(Me)(NH2Ph)][OTf][BAr′4] (BAr′4 = tetrakis[(3,5‐bis‐trifluoromethyl)phenyl]borate), [(tbpy)2Rh(Me)(NHPh)][BAr′4], [(tbpy)2Rh(OMe)(Cl)]Cl, and [(bpy)Rh(X)2][PF6] (bpy = 2,2′‐bipyridyl; X = OH, OMe) have been synthesized and characterized by 1H, 13C{1H}, and 19F NMR spectroscopy, elemental analysis, or high‐resolution mass spectrometry as well as single‐crystal X‐ray diffraction for some complexes. A comparison of the solid‐state structural data for [(tbpy)2Rh(Me)(NH2Ph)]2+, [(tbpy)2Rh(NH2Ph)2]3+, [(tbpy)2Rh(NHPh)2]+, and [(tbpy)2Rh(NHPh)(NH2Ph)]2+ is included.

Idioma: Inglés

DOI: 10.1002/ejic.201403147

Año: 2015

Publicado en: European Journal of Inorganic Chemistry 2015, 6 (2015), 1041-1052
ISSN: 1434-1948

Factor impacto JCR: 2.686 (2015)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 12 / 46 = 0.261 (2015) - Q2 - T1

Factor impacto SCIMAGO: 0.983 - Inorganic Chemistry (Q1)

Tipo y forma: Article (Published version)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)