Resumen: The hexanuclear gold carbonyl cluster [PPh4]2[Au6(CF3)6Br2(CO)2] (4) has been obtained by spontaneous self-assembly of the following independent units: CF3AuCO (1) and [PPh4][Br(AuCF3)2] (3). The cyclo-Au6 aggregate 4, in which the components are held together by unassisted, fairly strong aurophilic interactions (Au¿Au ~310 pm), exhibits a cyclohexane-like arrangement with chair conformation. These aurophilic interactions also result in significant ¿(CO) lowering: from 2194 cm-1 in the separate component 1 to 2171 cm-1 in the mixed aggregate 4. Procedures to prepare the single-bridged dinuclear component 3 as well as the mononuclear derivative [PPh4][CF3AuBr] (2) are also reported. Idioma: Inglés DOI: 10.1039/c5sc01578b Año: 2015 Publicado en: Chemical Science 6, 10 (2015), 5506-5510 ISSN: 2041-6520 Factor impacto JCR: 9.144 (2015) Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 14 / 163 = 0.086 (2015) - Q1 - T1 Factor impacto SCIMAGO: 4.647 - Chemistry (miscellaneous) (Q1)