Recent Advances on Asymmetric Nitroso Aldol Reaction
Merino, P. (Universidad de Zaragoza) ; Tejero, T. (Universidad de Zaragoza) ; Delso, I. (Universidad de Zaragoza) ; Matute, R. (Universidad de Zaragoza)
Resumen: The reaction of aromatic nitroso derivatives with enolizable carbonyl compounds (nitroso aldol reaction) to give either a-hydroxyamino or a-aminoxy carbonyl compounds is an important synthetic method. This review illustrates the recent advances in rendering the process regio- and enantioselective as well as catalytic. By employing metal and organic catalysts a range of a-amino (a-oxyamination) and a-hydroxy (a-aminoxylation) carbonyl derivatives can be generated with total regioselectivity and high levels of enantiomeric excess.
Idioma: Inglés
DOI: 10.1055/s-0035-1561505
Año: 2016
Publicado en: SYNTHESIS-STUTTGART 48, 5 (2016), 653-676
ISSN: 0039-7881
Factor impacto JCR: 2.65 (2016)
Categ. JCR: CHEMISTRY, ORGANIC rank: 22 / 59 = 0.373 (2016) - Q2 - T2
Factor impacto SCIMAGO: 1.066 - Organic Chemistry (Q1) - Catalysis (Q2)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E10
Financiación: info:eu-repo/grantAgreement/ES/MICINN/CTQ2013-44367-C2-1-P
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Orgánica (Dpto. Química Orgánica)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
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Idioma: Inglés
DOI: 10.1055/s-0035-1561505
Año: 2016
Publicado en: SYNTHESIS-STUTTGART 48, 5 (2016), 653-676
ISSN: 0039-7881
Factor impacto JCR: 2.65 (2016)
Categ. JCR: CHEMISTRY, ORGANIC rank: 22 / 59 = 0.373 (2016) - Q2 - T2
Factor impacto SCIMAGO: 1.066 - Organic Chemistry (Q1) - Catalysis (Q2)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E10
Financiación: info:eu-repo/grantAgreement/ES/MICINN/CTQ2013-44367-C2-1-P
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Orgánica (Dpto. Química Orgánica)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. Exportado de SIDERAL (2020-02-21-13:29:12)
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Record created 2017-01-13, last modified 2020-02-21