A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour

Campo Ruiz, Jesus Javier (Universidad de Zaragoza) ; Falvello, Lawrence Rocco (Universidad de Zaragoza) ; Forcén, Elena ; Sáenz de Pipaón, Cristina ; Palacio, Fernando (Universidad de Zaragoza) ; Tomás, Milagros

Resumen: A newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(II) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the Co4O4 cores preserved. The octahedrally coordinated Co(II) bridges are implicated in the onset of magnetic order at an experimentally accessible temperature.

Idioma: Inglés

DOI: 10.1039/c6dt02652d

Año: 2016

Publicado en: Dalton Transactions 45 (2016), 16764 [5 pp]
ISSN: 1477-9226

Factor impacto JCR: 4.029 (2016)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 7 / 46 = 0.152 (2016) - Q1 - T1

Factor impacto SCIMAGO: 1.229 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/M4
Financiación: info:eu-repo/grantAgreement/ES/MEC/FPU-AP2009-4211
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2015-68200-C2-1-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2015-68200-C2-2-P

Tipo y forma: Article (Published version)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)