Effect of the presence of hydrogen sulphide on the formation of light gases, soot and PAH during the pyrolysis of ethylene
Viteri Moya, Fausto ; Sánchez, Adrián ; Millera, Ángela (Universidad de Zaragoza) ; Bilbao, Rafael (Universidad de Zaragoza) ; Alzueta, María U. (Universidad de Zaragoza)
Resumen: The formation of light gases, soot, and 16 polycyclic aromatic hydrocarbons (EPA-PAH), classified as priority pollutants by the United States Environmental Protection Agency (USEPA), has been studied during the pyrolysis of mixtures of ethylene with hydrogen sulfide (H2S) in a tubular flow reactor setup. The study was made using a constant concentration of ethylene and different inlet concentrations of H2S, in a temperature range from 1075 to 1475 K. The light gases produced were quantified by a chromatographic method. The soot amount formed was also quantified at the outlet of the reactor. The speciation of the individual EPA-PAH compounds was made by a combination of Soxhlet extraction, extract concentration by a rotary evaporator, and gas chromatography coupled to mass spectrometry. The present study shows that, under pyrolysis conditions, there is an effective interaction between H2S and hydrocarbons, forming significant amounts of CS2 and bonding sulfur to soot. The presence of H2S in the pyrolysis of ethylene contributes to slightly decrease the formation of soot and EPA- PAH, which indicates a positive effect of the sulfur compound under pyrolysis conditions.
Idioma: Inglés
DOI: 10.1021/acs.energyfuels.6b01271
Año: 2016
Publicado en: Energy and Fuels 30, 11 (2016), 9745–9751
ISSN: 0887-0624
Factor impacto JCR: 3.091 (2016)
Categ. JCR: ENGINEERING, CHEMICAL rank: 27 / 135 = 0.2 (2016) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 33 / 92 = 0.359 (2016) - Q2 - T2
Factor impacto SCIMAGO: 1.258 - Chemical Engineering (miscellaneous) (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-65226
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
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Idioma: Inglés
DOI: 10.1021/acs.energyfuels.6b01271
Año: 2016
Publicado en: Energy and Fuels 30, 11 (2016), 9745–9751
ISSN: 0887-0624
Factor impacto JCR: 3.091 (2016)
Categ. JCR: ENGINEERING, CHEMICAL rank: 27 / 135 = 0.2 (2016) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 33 / 92 = 0.359 (2016) - Q2 - T2
Factor impacto SCIMAGO: 1.258 - Chemical Engineering (miscellaneous) (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-65226
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2020-02-21-13:16:49)
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Record created 2017-09-07, last modified 2020-02-21