Resumen: Recent reports on homogeneous catalytic hydrosilylation suggest that this reac- tion may not always operate by the generally accepted classical catalytic cycles. Ionic and concerted outer-sphere mechanisms are broadly accepted in hydrogenation catalysis; however, they have been barely reported for catalytic hydrosilylation. Mechanistic studies hint at the heterolytic splitting of Si–H bonds as initial step of the non-classical catalytic cycle.
Idioma: Español
Año: 2015
Publicado en: Revista de la Academia de Ciencias Exactas, Físico-Químicas y Naturales de Zaragoza 70 (2015), 39–57
ISSN: 0370-3207
Financiación: info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CTQ2011-27593
Financiación: info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-0050
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
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Idioma: Español
Año: 2015
Publicado en: Revista de la Academia de Ciencias Exactas, Físico-Químicas y Naturales de Zaragoza 70 (2015), 39–57
ISSN: 0370-3207
Financiación: info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CTQ2011-27593
Financiación: info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-0050
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2017-12-13-12:08:23)
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