Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: Unveiling the role of the oxidant

Iturmendi, Amaia ; Iglesias, Manuel ; Munárriz, Julen (Universidad de Zaragoza) ; Polo, Víctor (Universidad de Zaragoza) ; Pérez-Torrente, Jesús J. (Universidad de Zaragoza) ; Oro, Luis A. (Universidad de Zaragoza)

Resumen: The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.

Idioma: Inglés

DOI: 10.1039/c6cc09133d

Año: 2017

Publicado en: Chemical Communications 53, 2 (2017), 404-407
ISSN: 1359-7345

Factor impacto JCR: 6.29 (2017)

Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 28 / 169 = 0.166 (2017) - Q1 - T1

Factor impacto SCIMAGO: 2.555 - Catalysis (Q1) - Ceramics and Composites (Q1) - Chemistry (miscellaneous) (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Electronic, Optical and Magnetic Materials (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E07
Financiación: info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-0050
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2013-42532-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P

Tipo y forma: Article (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
Área (Departamento): Área Química Física (Dpto. Química Física)