000078126 001__ 78126
000078126 005__ 20210208180159.0
000078126 0247_ $$2doi$$a10.1016/j.arabjc.2018.01.022
000078126 0248_ $$2sideral$$a110633
000078126 037__ $$aART-2019-110633
000078126 041__ $$aeng
000078126 100__ $$aOrtiz, R.
000078126 245__ $$aFunctionalization of p-activated alcohols by trapping carbocations in pure water under smooth conditions
000078126 260__ $$c2019
000078126 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078126 5203_ $$aAcetic acid as catalyst in pure water was found to be an excellent reaction medium for the direct dehydrative functionalization of p-activated alcohols using a wide variety of interesting C-, P-, and S-centered nucleophiles, such as indoles, pyrrole, anilines, 1, 3-dicarbonyl compounds, diphenyl phosphite and pyridine-2-thiol. The smooth reaction conditions, along with high yields, short reaction times, clean reaction crudes, an easy product isolation procedure, plus the reusability of the catalyst and the use of no excess of nucleophiles, make this approach an atom economical, green and appealing method to efficiently trap carbocations in pure water, leading to new Csp3 X bonds (X = Csp2, Csp3, P and S).
000078126 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E104$$9info:eu-repo/grantAgreement/ES/DGA-FSE/E77$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2017-88091-P
000078126 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000078126 590__ $$a4.762$$b2019
000078126 592__ $$a0.779$$b2019
000078126 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b45 / 177 = 0.254$$c2019$$dQ2$$eT1
000078126 593__ $$aChemistry (miscellaneous)$$c2019$$dQ1
000078126 593__ $$aChemical Engineering (miscellaneous)$$c2019$$dQ1
000078126 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000078126 700__ $$aKoukouras, A.
000078126 700__ $$0(orcid)0000-0001-6832-8983$$aMarqués-López, E.$$uUniversidad de Zaragoza
000078126 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, R.$$uUniversidad de Zaragoza
000078126 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000078126 773__ $$g13, 1 (2019), 1866-1873$$pARABIAN JOURNAL OF CHEMISTRY$$tARABIAN JOURNAL OF CHEMISTRY$$x1878-5352
000078126 8564_ $$s1155801$$uhttps://zaguan.unizar.es/record/78126/files/texto_completo.pdf$$yVersión publicada
000078126 8564_ $$s91131$$uhttps://zaguan.unizar.es/record/78126/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000078126 909CO $$ooai:zaguan.unizar.es:78126$$particulos$$pdriver
000078126 951__ $$a2021-02-08-17:42:32
000078126 980__ $$aARTICLE