Generation of gold nanoclusters encapsulated in an MCM-22 zeolite for the aerobic oxidation of cyclohexane
Liu, L. ; Arenal, R. (Universidad de Zaragoza) ; Meira, D.M. ; Corma, A.
Resumen: In this work, we will report the generation of Au clusters in a purely siliceous MCM-22 zeolite. The catalytic properties of these Au clusters have been tested for the selective oxidation of cyclohexane to cyclohexanol and cyclohexanone (KA-oil). The Au clusters encapsulated in the MCM-22 zeolite are highly active and selective for the oxidation of cyclohexane to KA-oil, which is superior to Au nanoparticles on the same support. These results suggest that Au clusters are highly active for the activation of oxygen to produce radical species.
Idioma: Inglés
DOI: 10.1039/c8cc07185c
Año: 2019
Publicado en: CHEMICAL COMMUNICATIONS 55, 11 (2019), 1607-1610
ISSN: 1359-7345
Factor impacto JCR: 5.996 (2019)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 34 / 177 = 0.192 (2019) - Q1 - T1
Factor impacto SCIMAGO: 1.992 - Catalysis (Q1) - Ceramics and Composites (Q1) - Chemistry (miscellaneous) (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Electronic, Optical and Magnetic Materials (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2016-79776-P
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2020-07-16-09:28:36)
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Idioma: Inglés
DOI: 10.1039/c8cc07185c
Año: 2019
Publicado en: CHEMICAL COMMUNICATIONS 55, 11 (2019), 1607-1610
ISSN: 1359-7345
Factor impacto JCR: 5.996 (2019)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 34 / 177 = 0.192 (2019) - Q1 - T1
Factor impacto SCIMAGO: 1.992 - Catalysis (Q1) - Ceramics and Composites (Q1) - Chemistry (miscellaneous) (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Electronic, Optical and Magnetic Materials (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2016-79776-P
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2020-07-16-09:28:36)
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Record created 2019-03-13, last modified 2020-07-16