000078266 001__ 78266
000078266 005__ 20200811091508.0
000078266 0247_ $$2doi$$a10.1021/acs.organomet.7b00750
000078266 0248_ $$2sideral$$a104175
000078266 037__ $$aART-2018-104175
000078266 041__ $$aeng
000078266 100__ $$aKaratas, M.O.
000078266 245__ $$aPentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands
000078266 260__ $$c2018
000078266 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078266 5203_ $$aNew coumarin-Tethered benzimidazolium (BzICouRHCl) and imidazolium (ICouRHCl) salts have been prepared as precursors for coumarin-NHC rhodium(I) complexes RhCl(NHC)(cod). Trigonal bypiramidal pentacoordinated bis-coumarin-NHC rhodium(I) species, RhCl(NHC)2, can be obtained by heating rhodium-cod derivatives in the presence of coumarin-Azolium salts and a base. These unusual species are stabilized by coordination of the unsaturated bond of both coumarin moieties by the same enantioface. The allyl substituent on doubly functionalized NHC competes for coordination with coumarin wingtips. DFT calculations upon coordination of the olefin moieties support the experimental results.
000078266 536__ $$9info:eu-repo/grantAgreement/ES/CSIC/201680I011$$9info:eu-repo/grantAgreement/ES/DGA/E07$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2013-42532-P$$9info:eu-repo/grantAgreement/ES/MINECO/IJCI-2015-27029
000078266 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000078266 590__ $$a4.1$$b2018
000078266 591__ $$aCHEMISTRY, ORGANIC$$b11 / 57 = 0.193$$c2018$$dQ1$$eT1
000078266 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b5 / 45 = 0.111$$c2018$$dQ1$$eT1
000078266 592__ $$a1.473$$b2018
000078266 593__ $$aInorganic Chemistry$$c2018$$dQ1
000078266 593__ $$aPhysical and Theoretical Chemistry$$c2018$$dQ1
000078266 593__ $$aOrganic Chemistry$$c2018$$dQ1
000078266 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000078266 700__ $$0(orcid)0000-0002-3666-5800$$aDi Giuseppe, A.$$uUniversidad de Zaragoza
000078266 700__ $$0(orcid)0000-0002-1735-6439$$aPassarelli, V.
000078266 700__ $$aAllcl, B.
000078266 700__ $$0(orcid)0000-0002-3327-0918$$aPérez-Torrente, J.J.$$uUniversidad de Zaragoza
000078266 700__ $$0(orcid)0000-0001-7154-7239$$aOro, L.A.$$uUniversidad de Zaragoza
000078266 700__ $$aÖzdemir, I.
000078266 700__ $$0(orcid)0000-0003-4460-8678$$aCastarlenas, R.$$uUniversidad de Zaragoza
000078266 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000078266 773__ $$g37, 2 (2018), 191-202$$pOrganometallics$$tOrganometallics$$x0276-7333
000078266 8564_ $$s590979$$uhttps://zaguan.unizar.es/record/78266/files/texto_completo.pdf$$yPostprint
000078266 8564_ $$s116825$$uhttps://zaguan.unizar.es/record/78266/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000078266 909CO $$ooai:zaguan.unizar.es:78266$$particulos$$pdriver
000078266 951__ $$a2020-08-11-09:03:21
000078266 980__ $$aARTICLE