000079523 001__ 79523
000079523 005__ 20191127155500.0
000079523 0247_ $$2doi$$a10.3390/molecules23112887
000079523 0248_ $$2sideral$$a109011
000079523 037__ $$aART-2018-109011
000079523 041__ $$aeng
000079523 100__ $$0(orcid)0000-0002-2676-8814$$aPires, Elisabet$$uUniversidad de Zaragoza
000079523 245__ $$aOptimization of the synthesis of glycerol derived monoethers from glycidol by means of heterogeneous acid catalysis
000079523 260__ $$c2018
000079523 5060_ $$aAccess copy available to the general public$$fUnrestricted
000079523 5203_ $$aWe present an efficient and green methodology for the synthesis of glycerol monoethers, starting from glycidol and different alcohols, by means of heterogeneous acid catalysis. A scope of Brønsted and Lewis acid catalysts were applied to the benchmark reaction of glycidol and methanol. The selected catalysts were cationic exchangers, such as Nafion NR50, Dowex 50WX2, Amberlyst 15 and K10-Montmorillonite, both in their protonic form and exchanged with Al(III), Zn(II) and Fe(III). Thus, total conversions were reached in short times by using 1 and 5% mol catalyst loading and room temperature, without the need for excess glycidol or the presence of a solvent. Finally, these conditions and the best catalysts were successfully applied to the reaction of glycidol with several alcohols such as butanol or isopropanol.
000079523 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E37-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52367-R
000079523 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000079523 590__ $$a3.06$$b2018
000079523 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b67 / 172 = 0.39$$c2018$$dQ2$$eT2
000079523 591__ $$aBIOCHEMISTRY & MOLECULAR BIOLOGY$$b133 / 294 = 0.452$$c2018$$dQ2$$eT2
000079523 592__ $$a0.757$$b2018
000079523 593__ $$aAnalytical Chemistry$$c2018$$dQ1
000079523 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1
000079523 593__ $$aDrug Discovery$$c2018$$dQ1
000079523 593__ $$aPhysical and Theoretical Chemistry$$c2018$$dQ1
000079523 593__ $$aMolecular Medicine$$c2018$$dQ1
000079523 593__ $$aOrganic Chemistry$$c2018$$dQ1
000079523 593__ $$aPharmaceutical Science$$c2018$$dQ1
000079523 593__ $$aMedicine (miscellaneous)$$c2018$$dQ1
000079523 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000079523 700__ $$0(orcid)0000-0003-1199-2087$$aGarcía, José Ignacio
000079523 700__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, Alejandro
000079523 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral, José Antonio$$uUniversidad de Zaragoza
000079523 700__ $$aGarcía-Peiro, José Ignacio
000079523 700__ $$aVelázquez, David
000079523 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000079523 773__ $$g23, 11 (2018), [10 pp]$$pMolecules$$tMolecules$$x1420-3049
000079523 8564_ $$s505010$$uhttps://zaguan.unizar.es/record/79523/files/texto_completo.pdf$$yVersión publicada
000079523 8564_ $$s100630$$uhttps://zaguan.unizar.es/record/79523/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000079523 909CO $$ooai:zaguan.unizar.es:79523$$particulos$$pdriver
000079523 951__ $$a2019-11-27-15:49:42
000079523 980__ $$aARTICLE