000084689 001__ 84689
000084689 005__ 20200716101511.0
000084689 0247_ $$2doi$$a10.1002/ejic.201800985
000084689 0248_ $$2sideral$$a109079
000084689 037__ $$aART-2019-109079
000084689 041__ $$aeng
000084689 100__ $$aMonteagudo-Olivan, R.
000084689 245__ $$aSolvent-Free Encapsulation at High Pressure with Carboxylate-Based MOFs
000084689 260__ $$c2019
000084689 5060_ $$aAccess copy available to the general public$$fUnrestricted
000084689 5203_ $$aThe solvent-free encapsulation of caffeine and kojic acid was carried out in different carboxylate-based MOFs [MIL-53(Al), UiO-66 and Mg-MOF-74] by high pressure (0.32 GPa) contact. This methodology enables fast and ecofriendly encapsulation and gives rise to additive@MOFs with physical and features equivalent to those of materials obtained by common liquid phase encapsulation processes. It could be applied to other host–guest systems, simplifying the procedures, reducing the use and waste of harmful chemicals, and approaching the conditions of interest in the industry. The characterization carried out by thermogravimetry, X-ray diffraction, N2 adsorption, and 13C NMR provided information about the presence and conformation of the additives in the MOFs. The highest encapsulation values for caffeine (37 %) and kojic acid (32 %) were obtained with MIL-53(Al).
000084689 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/T43-17R
000084689 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000084689 590__ $$a2.529$$b2019
000084689 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b16 / 45 = 0.356$$c2019$$dQ2$$eT2
000084689 592__ $$a0.693$$b2019
000084689 593__ $$aInorganic Chemistry$$c2019$$dQ1
000084689 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000084689 700__ $$0(orcid)0000-0003-2006-1495$$aPaseta, L.$$uUniversidad de Zaragoza
000084689 700__ $$aPotier, G.
000084689 700__ $$0(orcid)0000-0001-8105-2432$$aLópez-Ram-de-Viu, P.$$uUniversidad de Zaragoza
000084689 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000084689 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000084689 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000084689 773__ $$g2019, 1 (2019), 29-36$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000084689 8564_ $$s1727342$$uhttps://zaguan.unizar.es/record/84689/files/texto_completo.pdf$$yPostprint
000084689 8564_ $$s67649$$uhttps://zaguan.unizar.es/record/84689/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000084689 909CO $$ooai:zaguan.unizar.es:84689$$particulos$$pdriver
000084689 951__ $$a2020-07-16-09:18:39
000084689 980__ $$aARTICLE