000088255 001__ 88255
000088255 005__ 20220711095452.0
000088255 0247_ $$2doi$$a10.3390/catal10030333
000088255 0248_ $$2sideral$$a116721
000088255 037__ $$aART-2020-116721
000088255 041__ $$aeng
000088255 100__ $$0(orcid)0000-0001-5835-1223$$aOrtega-Liébana, M. Carmen
000088255 245__ $$aGold-Based Nanoparticles on Amino-Functionalized Mesoporous Silica Supports as Nanozymes for Glucose Oxidation
000088255 260__ $$c2020
000088255 5060_ $$aAccess copy available to the general public$$fUnrestricted
000088255 5203_ $$aThe transformation of glucose represents a topic of great interest at different levels. In the first place, glucose is currently conceived as a green feedstock for the sustainable production of chemicals. Secondly, the depletion of glucose at the cellular level is currently envisioned as a promising strategy to treat and alter the erratic metabolism of tumoral cells. The use of natural enzymes offers multiple advantages in terms of specificity towards the glucose substrate but may lack sufficient robustness and recyclability beyond the optimal operating conditions of these natural systems. In the present work, we have evaluated the potential use of an inorganic based nanohybrid containing gold nanoparticles supported onto ordered mesoporous supports. We have performed different assays that corroborate the enzyme-mimicking response of these inorganic surrogates towards the selective conversion of glucose into gluconic acid and hydrogen peroxide. Moreover, we conclude that these enzyme-like mimicking surrogates can operate at different pH ranges and under mild reaction conditions, can be recycled multiple times and maintain excellent catalytic response in comparison with other gold-based catalysts.
000088255 536__ $$9info:eu-repo/grantAgreement/EC/H2020/742684/EU/Catalytic Dual-Function Devices Against Cancer/CADENCE$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 742684-CADENCE
000088255 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000088255 590__ $$a4.146$$b2020
000088255 591__ $$aCHEMISTRY, PHYSICAL$$b67 / 162 = 0.414$$c2020$$dQ2$$eT2
000088255 592__ $$a0.8$$b2020
000088255 593__ $$aPhysical and Theoretical Chemistry$$c2020$$dQ2
000088255 593__ $$aCatalysis$$c2020$$dQ2
000088255 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000088255 700__ $$0(orcid)0000-0002-1791-0188$$aBonet-Aleta, Javier$$uUniversidad de Zaragoza
000088255 700__ $$0(orcid)0000-0002-4546-4111$$aHueso, José L.
000088255 700__ $$0(orcid)0000-0002-8701-9745$$aSantamaría, Jesús$$uUniversidad de Zaragoza
000088255 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000088255 773__ $$g10, 3 (2020), 333 1-15$$pCatalysts$$tCatalysts$$x2073-4344
000088255 85641 $$uhttps://www.mdpi.com/2073-4344/10/3/333$$zTexto completo de la revista
000088255 8564_ $$s2505374$$uhttps://zaguan.unizar.es/record/88255/files/texto_completo.pdf$$yVersión publicada
000088255 8564_ $$s454028$$uhttps://zaguan.unizar.es/record/88255/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000088255 909CO $$ooai:zaguan.unizar.es:88255$$particulos$$pdriver
000088255 951__ $$a2022-07-11-09:06:36
000088255 980__ $$aARTICLE