Designed asymmetric coordination helicates with bis-beta-diketonate ligands

Diego, R ; Darawsheh, M ; Barrios, LA ; Sadurni, A ; Garcia, J ; Lloyd-Williams, P ; Teat, SJ ; Roubeau, O (Universidad de Zaragoza) ; Aquila, D ; Aromi, G

Resumen: A new bis-(beta-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(III) and Ga(III) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups.

Idioma: Inglés

DOI: 10.1039/c9dt03398j

Año: 2019

Publicado en: Dalton Transactions 48, 45 (2019), 16844-16847
ISSN: 1477-9226

Factor impacto JCR: 4.174 (2019)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 5 / 45 = 0.111 (2019) - Q1 - T1

Factor impacto SCIMAGO: 1.048 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/MICINN/PCI2018-093106
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PGC2018-098630-B-I00
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/MAT2017-86826-R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/IJCI-2016-29901

Tipo y forma: Article (PostPrint)

Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)