000097082 001__ 97082
000097082 005__ 20210902121627.0
000097082 0247_ $$2doi$$a10.1039/c9mh01594a
000097082 0248_ $$2sideral$$a117235
000097082 037__ $$aART-2020-117235
000097082 041__ $$aeng
000097082 100__ $$0(orcid)0000-0002-8424-9780$$aUrtizberea, Ainhoa$$uUniversidad de Zaragoza
000097082 245__ $$aVanadyl spin qubit 2D arrays and their integration on superconducting resonators
000097082 260__ $$c2020
000097082 5060_ $$aAccess copy available to the general public$$fUnrestricted
000097082 5203_ $$aVanadyl systems have been shown to possess superior quantum coherence among molecular spin qubits. Meanwhile two-dimensional (2D) networks of spin qubit nodes could provide a means to achieve the control of qubit localization and orientation required for implementation of molecular spin qubits in hybrid solid-state devices. Here, the 2D metal-organic framework [{VO(TCPP)}Zn2(H2O)2]8 is reported and its vanadyl porphyrin node is shown to exhibit superior spin dynamics and to enable coherent spin manipulations, making it a valid spin qubit candidate. Nanodomains of the MOF 2D coordination planes are efficiently formed at the air-water interface, first under Langmuir-Schaefer conditions, allowing mono- and multiple layer deposits to be transferred to a variety of substrates. Similar nanodomains are then successfully formed in situ on the surface of Nb superconducting coplanar resonators. Transmission measurements with a resonator with a 14 µm-wide constriction allow to estimate that the single spin-photon coupling G1 of the vanadyl spins in the nanodomains is close to being optimal, at ca. 0.5 Hz. Altogether, these results provide the basis for developing a viable hybrid quantum computing architecture.
000097082 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E09-17R$$9info:eu-repo/grantAgreement/ES/DGA/E31-17R$$9info:eu-repo/grantAgreement/ES/MEC/FPU14-05367$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-096075-B-C21$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-64486-R$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/MAT2017-86826-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R$$9info:eu-repo/grantAgreement/ES/MINECO/PCI2018-093116
000097082 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000097082 590__ $$a13.266$$b2020
000097082 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b19 / 178 = 0.107$$c2020$$dQ1$$eT1
000097082 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b26 / 333 = 0.078$$c2020$$dQ1$$eT1
000097082 592__ $$a4.322$$b2020
000097082 593__ $$aElectrical and Electronic Engineering$$c2020$$dQ1
000097082 593__ $$aProcess Chemistry and Technology$$c2020$$dQ1
000097082 593__ $$aMechanics of Materials$$c2020$$dQ1
000097082 593__ $$aMaterials Science (miscellaneous)$$c2020$$dQ1
000097082 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000097082 700__ $$0(orcid)0000-0003-2553-0633$$aNatividad, Eva$$uUniversidad de Zaragoza
000097082 700__ $$0(orcid)0000-0003-3449-4929$$aAlonso, Pablo J.
000097082 700__ $$aPérez-Martínez, Laura
000097082 700__ $$0(orcid)0000-0003-3691-3437$$aAndrés, Miguel A.$$uUniversidad de Zaragoza
000097082 700__ $$0(orcid)0000-0002-3492-6456$$aGascón, Ignacio$$uUniversidad de Zaragoza
000097082 700__ $$0(orcid)0000-0002-6184-3920$$aGimeno, Ignacio
000097082 700__ $$0(orcid)0000-0001-6284-0521$$aLuis, Fernando$$uUniversidad de Zaragoza
000097082 700__ $$0(orcid)0000-0003-2095-5843$$aRoubeau, Olivier$$uUniversidad de Zaragoza
000097082 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000097082 7102_ $$15001$$2065$$aUniversidad de Zaragoza$$bDpto. Ciencia Tecnol.Mater.Fl.$$cÁrea Cienc.Mater. Ingen.Metal.
000097082 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000097082 773__ $$g7, 3 (2020), 885-897$$pMater. horizons$$tMaterials Horizons$$x2051-6347
000097082 8564_ $$s1807546$$uhttps://zaguan.unizar.es/record/97082/files/texto_completo.pdf$$yPostprint
000097082 8564_ $$s672001$$uhttps://zaguan.unizar.es/record/97082/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000097082 909CO $$ooai:zaguan.unizar.es:97082$$particulos$$pdriver
000097082 951__ $$a2021-09-02-08:50:40
000097082 980__ $$aARTICLE