Can aldehyde accumulation rates of red winesundergoing oxidation be predicted inaccelerated conditions? The controverted roleof aldehyde–polyphenol reactivity

Marrufo Curtido, Almudena (Universidad de Zaragoza) ; Ferreira, V. ; Escudero Carra, Ana María (Universidad de Zaragoza)

Resumen: BACKGROUND: The accumulation of acetaldehyde and Strecker aldehydes during wine oxidation is detrimental to quality and often determines wine shelf-life. Knowing in advance the specific tendency of a wine to accumulate these compounds would help decision making during winemaking. An accelerated test based on a forced oxidation procedure at 45 °C (5 days) to measure aldehyde accumulation rates (AARs) is proposed and assessed by comparing results with those obtained by oxidation at 25 °C (36 days). Reactivities of aldehydes in those same wines stored in anoxia at both temperatures were also measured. RESULTS: Wine oxygen consumption rates at 25 °C are poorly correlated with those observed at 45 °C. By contrast, AARs of methional and of 2- and 3-methylbutanals measured during wine oxidation at 25 °C are equivalent to those measured at 45 °C. AARs from isobutanal and acetaldehyde are also correlated, while AARs from phenylacetaldehyde are not. Partial least squares models explaining AARs show intriguing differences regarding the apparent limiting role played by wine anthocyanins and other polyphenols in the ability of wines to accumulate aldehydes. Measured differences in aldehyde pattern are similar to those of the other Strecker aldehydes. CONCLUSION: The proposed assay makes it possible to obtain a reasonable estimate of a wine’s tendency to accumulate aldehydes, with the exception phenylacetaldehyde, in 5 days. Neither differences in aldehyde reactivity between wines nor the change in reactivities with temperature support a major role for reactivity in differentially limiting AARs during wine oxidation. © 2021 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Idioma: Inglés

DOI: 10.1002/jsfa.11736

Año: 2022

Publicado en: Journal of the science of food and agriculture 102, 9 (2022), 3869-3878
ISSN: 0022-5142

Factor impacto JCR: 4.1 (2022)

Categ. JCR: AGRICULTURE, MULTIDISCIPLINARY rank: 11 / 58 = 0.19 (2022) - Q1 - T1
Categ. JCR: CHEMISTRY, APPLIED rank: 20 / 72 = 0.278 (2022) - Q2 - T1
Categ. JCR: FOOD SCIENCE & TECHNOLOGY rank: 47 / 142 = 0.331 (2022) - Q2 - T2

Factor impacto CITESCORE: 8.2 - Agricultural and Biological Sciences (Q1) - Nursing (Q1) - Biochemistry, Genetics and Molecular Biology (Q1)

Factor impacto SCIMAGO: 0.747 - Food Science (Q1) - Agronomy and Crop Science (Q1) - Nutrition and Dietetics (Q2) - Biotechnology (Q2)

Financiación: info:eu-repo/grantAgreement/ES/MINECO/AGL2014-59840
Financiación: info:eu-repo/grantAgreement/ES/MINECO/AGL2017-87373-C3-1-R

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Química Analítica (Dpto. Química Analítica)