Solvent-exchange process in MOF ultrathin films and its effect on CO2 and methanol adsorption
Andrés, M.A. ; Fontaine, P. ; Goldmann, M. ; Serre, C. ; Roubeau, O. ; Gascón, I. (Universidad de Zaragoza)
Resumen: Metal-organic framework (MOF) activation is crucial for the use of MOFs in several applications and solvent-exchange process is a necessary step in many activation methods. In this contribution, we have explored in situ MOF monolayer film formation at the air-water interface. Nanoparticles (NPs) of the Al trimesate MIL-96(Al) retain chloroform into their micropores, which considerably diminishes the CO2 adsorption capacity of MOF films. However, a solvent-exchange process between chloroform and water increases CO2 film adsorption capacity by 30%. Total Reflection X-Ray Fluorescence (TRXF) allows studying the kinetics of this process at the air-water interface, that strongly depends on the NP size. The conclusions derived from in situ studies allow optimizing the ex situ activation procedure of MIL-96(Al) films deposited onto quartz crystal microbalance (QCM) substrates in order to maximize CO2 and methanol adsorption.
Idioma: Inglés
DOI: 10.1016/j.jcis.2021.01.030
Año: 2021
Publicado en: Journal of Colloid and Interface Science 590 (2021), 72-81
ISSN: 0021-9797
Factor impacto JCR: 9.965 (2021)
Categ. JCR: CHEMISTRY, PHYSICAL rank: 33 / 165 = 0.2 (2021) - Q1 - T1
Factor impacto CITESCORE: 14.5 - Chemical Engineering (Q1) - Materials Science (Q1)
Factor impacto SCIMAGO: 1.397 - Biomaterials (Q1) - Surfaces, Coatings and Films (Q1) - Colloid and Surface Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/E31-17R
Financiación: info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2
Financiación: info:eu-repo/grantAgreement/ES/MEC/FPU14-05367
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R
Financiación: info:eu-repo/grantAgreement/ES/UZ/JIUZ-2015-CIE-02
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Física (Dpto. Química Física)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
Exportado de SIDERAL (2023-12-21-13:09:28)
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Idioma: Inglés
DOI: 10.1016/j.jcis.2021.01.030
Año: 2021
Publicado en: Journal of Colloid and Interface Science 590 (2021), 72-81
ISSN: 0021-9797
Factor impacto JCR: 9.965 (2021)
Categ. JCR: CHEMISTRY, PHYSICAL rank: 33 / 165 = 0.2 (2021) - Q1 - T1
Factor impacto CITESCORE: 14.5 - Chemical Engineering (Q1) - Materials Science (Q1)
Factor impacto SCIMAGO: 1.397 - Biomaterials (Q1) - Surfaces, Coatings and Films (Q1) - Colloid and Surface Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/E31-17R
Financiación: info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2
Financiación: info:eu-repo/grantAgreement/ES/MEC/FPU14-05367
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R
Financiación: info:eu-repo/grantAgreement/ES/UZ/JIUZ-2015-CIE-02
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Física (Dpto. Química Física)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2023-12-21-13:09:28)
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Record created 2023-12-21, last modified 2023-12-21