Recent advances on the chemistry of transition metal complexes with monoanionic bidentate silyl ligands
Batuecas, María (Universidad de Zaragoza) ; Goméz-España, Alejandra ; Fernández-Álvarez, Francisco J. (Universidad de Zaragoza)
Resumen: The chemistry of transition-metal (TM) complexes with monoanionic bidentate (κ2-L,Si) silyl ligands has considerably grown in recent years. This work summarizes the advances in the chemistry of TM-(κ2-L,Si) complexes (L=N-heterocycle, phosphine, N-heterocyclic carbene, thioether, ester, silylether or tetrylene). The most common synthetic method has been the oxidative addition of the Si−H bond to the metal center assisted by the coordination of L. The metal silicon bond distances in TM-(κ2-L,Si) complexes are in the range of metal-silyl bond distances. TM-(κ2-L,Si) complexes have proven to be effective catalysts for hydrosilylation and/or hydrogenation of unsaturated molecules among other processes.
Idioma: Inglés
DOI: 10.1002/cplu.202400162
Año: 2024
Publicado en: ChemPlusChem 89, 9 (2024), e202400162 [22 pp.]
ISSN: 2192-6506
Factor impacto JCR: 2.8 (2024)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 114 / 239 = 0.477 (2024) - Q2 - T2
Factor impacto SCIMAGO: 0.73 - Chemistry (miscellaneous) (Q2)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E42-23R
Financiación: info:eu-repo/grantAgreement/EC/H2020/101034288/EU/International Fellowship Programme for Talent Attraction to the Campus of International Excellence Campus Iberus/IberusExperience
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00
Tipo y forma: Review (Published version)
Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
Exportado de SIDERAL (2025-12-04-14:45:28)
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Idioma: Inglés
DOI: 10.1002/cplu.202400162
Año: 2024
Publicado en: ChemPlusChem 89, 9 (2024), e202400162 [22 pp.]
ISSN: 2192-6506
Factor impacto JCR: 2.8 (2024)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 114 / 239 = 0.477 (2024) - Q2 - T2
Factor impacto SCIMAGO: 0.73 - Chemistry (miscellaneous) (Q2)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E42-23R
Financiación: info:eu-repo/grantAgreement/EC/H2020/101034288/EU/International Fellowship Programme for Talent Attraction to the Campus of International Excellence Campus Iberus/IberusExperience
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00
Tipo y forma: Review (Published version)
Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2025-12-04-14:45:28)
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Record created 2024-09-06, last modified 2025-12-04