Overall and specific migration from multilayer high barrier food contact materials–kinetic study of cyclic polyester oligomers migration

Úbeda, S. (Universidad de Zaragoza) ; Aznar, M. (Universidad de Zaragoza) ; Vera, P. (Universidad de Zaragoza) ; Nerín, C. (Universidad de Zaragoza) ; Henríquez, L. ; Taborda, L. ; Restrepo, C.

Resumen: Most multilayer high barrier materials used in food packaging have a polyurethane adhesive layer in their structures. In order to assess the safety of these materials, it is important to determine the compounds intentionally added to the adhesives (IAS) as well as those non-intentionally added substances (NIAS). During the manufacture of polyurethane adhesives, some by-products can be formed, such as cyclic polyester oligomers coming from the reaction between dicarboxylic acids and glycols. Since these compounds are not listed in the Regulation 10/2011/EU, they should not be found in migration above 0.01 mg/kg of simulant. In this study two flexible multilayer packaging materials were used and migration was evaluated in simulant A (ethanol 10% v/v), simulant B (acetic acid 3% w/v) and simulant ethanol 95% v/v during 10 days at 60ºC. Identification and quantification of non-volatile compounds was carried out by UPLC-MS-QTOF. Most of migrants were oligomers such as cyclic polyesters and caprolactam oligomers. Overall migration and specific migration of adipic acid-diethylene glycol and phthalic acid-diethylene glycol were monitored over time and analysed by UPLC-MS-TQ. In most cases, ethanol 95% v/v was the simulant with the highest concentration values. Overall migration kinetics followed a similar pattern than specific migration kinetics.

Idioma: Inglés

DOI: 10.1080/19440049.2017.1346390

Año: 2017

Publicado en: Food Additives and Contaminants - Part A Chemistry, Analysis, Control, Exposure and Risk Assessment 34, 10 (2017), 1784-1794
ISSN: 1944-0049

Factor impacto JCR: 2.129 (2017)

Categ. JCR: CHEMISTRY, APPLIED rank: 30 / 70 = 0.429 (2017) - Q2 - T2
Categ. JCR: FOOD SCIENCE & TECHNOLOGY rank: 50 / 133 = 0.376 (2017) - Q2 - T2
Categ. JCR: TOXICOLOGY rank: 57 / 93 = 0.613 (2017) - Q3 - T2

Factor impacto SCIMAGO: 0.74 - Food Science (Q1) - Toxicology (Q2) - Medicine (miscellaneous) (Q2) - Public Health, Environmental and Occupational Health (Q2) - Chemistry (miscellaneous) (Q2) - Health, Toxicology and Mutagenesis (Q2)

Financiación: info:eu-repo/grantAgreement/ES/MINECO/AGL2012-37886
Financiación: info:eu-repo/grantAgreement/ES/MINECO/AGL2015-67362-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/RYC-2012-11856

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Analítica (Dpto. Química Analítica)
Área (Departamento): Proy. investigación HVA (Dpto. Química Analítica)