In-situ synthesis of hydrogen peroxide in tandem with selective oxidation reactions: a review

Puértolas Lacambra, Begoña ; Hill, Alf ; García Martínez, Tomás ; Solsona Espriú, Benjamín ; Torrente Murciano, Laura

Resumen: One-pot combination of the in-situ generation of hydrogen peroxide (H2O2) with selective oxidation reactions enhances the environmental and economic attractiveness of the use of H2O2 as green oxidant at industrial scale. This tandem reaction improves not only the safety aspects associated to H2O2 storage and transportation but also reduces the capital and operation costs. This review covers the progress in the field focussing on the areas of catalysis development, mechanistic understanding and engineering approaches (such as membrane reactors) for specific systems involving epoxidation of propylene oxide, hydroxylation of benzene, oxygenate synthesis from methane and Fenton processes, highlighting the main challenges to overcome in the near future.

Idioma: Inglés

DOI: 10.1016/j.cattod.2014.03.054

Año: 2015

Publicado en: Catalysis Today 248 (2015), 115–127
ISSN: 0920-5861

Factor impacto JCR: 4.312 (2015)

Categ. JCR: CHEMISTRY, APPLIED rank: 4 / 72 = 0.056 (2015) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 13 / 135 = 0.096 (2015) - Q1 - T1
Categ. JCR: CHEMISTRY, PHYSICAL rank: 34 / 144 = 0.236 (2015) - Q1 - T1

Factor impacto SCIMAGO: 1.335 - Chemistry (miscellaneous) (Q1) - Catalysis (Q2)

Financiación: info:eu-repo/grantAgreement/ES/FEDER/CTQ2012-37925-C03-2
Financiación: info:eu-repo/grantAgreement/ES/FEDER/CTQ2012-37984-C02-01
Financiación: info:eu-repo/grantAgreement/ES/MEC/FPU-AP2009-3544

Tipo y forma: Article (Published version)