From Imidazole toward Imidazolium Salts and N-Heterocyclic Carbene Ligands: Electronic and Geometrical Redistribution
Resumen: Investigations dealing with N-heterocyclic carbenes and their derivatives are usually centered on the influence that they exert by acting as catalysts, ionic liquids, or metallodrugs and consequently on their capabilities to tune the properties and reactivity of these systems. In this context, we aimed to focus on the internal molecular changes undergone by imidazole derivatives, from electronic and geometrical points of view. This work represents an empirical evidence of the molecular modifications that an imidazole skeleton undergoes upon protonation, alkylation, and metalation.
Idioma: Inglés
DOI: 10.1021/acsomega.7b00138
Año: 2017
Publicado en: ACS OMEGA 2, 4 (2017), 1392-1399
ISSN: 2470-1343

Factor impacto SCIMAGO: 0.749 - Chemical Engineering (miscellaneous) (Q1) - Chemistry (miscellaneous) (Q2)

Financiación: info:eu-repo/grantAgreement/ES/UZ/UZ2015-CIE-09
Tipo y forma: Article (Published version)
Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
Exportado de SIDERAL (2020-06-23-12:28:19)

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